Pre-prints
– Electrosteric Stabilization of End-on Cupric Superoxide Complexes
Alexander B. Weberg, Samuel P. McCollom, Neil C. Tomson
Chemrxiv, DOI: 10.26434/chemrxiv-2022-63pfg
– Electrostatic Contributions to the Stability of an End-on Cupric Superoxide
Alexander B. Weberg, Samuel P. McCollom, Ryan P. Murphy, Neil C. Tomson
Chemrxiv, DOI: 10.26434/chemrxiv-2022-lcb1w
Publications
46. Controlling the Size of Molecular Copper Clusters Supported by a Multinucleating Macrocycle
Qiuran Wang, Ryan P. Murphy, Michael R. Gau, Patrick J. Carroll, Neil C. Tomson
Inorganic Chemistry, 2024, in press. DOI: 10.1021/acs.inorgchem.4c02416
45. Reactivity Profile of a Formally Dicobalt(0) Complex Bound by a Redox-Active Macrocycle
Ariana Z. Spentzos, Shannon A. Ford, Breanna Muldowney, Tianchang Liu, Peng Cui, Michael R. Gau, Patrick J. Carroll, Neil C. Tomson
Organometallics, 2024, 43, 1425–1437. DOI: 10.1021/acs.organomet.4c00156
+ Invited for the Front Cover of the associated issue of this journal.
44. Influence of Metal Identity and Complex Nuclearity in Kumada Cross-Coupling Polymerizations with a Pyridine Diimine-Based Ligand Scaffold
Andrew J. King, Jiashu Wang, Tianchang Liu, Adharsh Raghavan, Neil C. Tomson, and Aleksandr V. Zhukhovitskiy
ACS Polymers Au, 2023, 3, 475-481. DOI: 10.1021/acspolymersau.3c00022
43. Anion Capture at the Open Core of a Geometrically Flexible Dicopper(II,II) Macrocycle Complex
Sam H. Brooks, Corey A. Richards, Patrick J. Carroll, Michael R. Gau, and Neil C. Tomson
Inorganics, 2023, 11, 348. DOI: 10.3390/inorganics11090348
+ Invited as part of the Special Issue Binuclear Complexes II.
42. Metallophilic and Inter-Ligand Interactions in Diargentous Compounds Bound by a Geometrically Flexible Macrocycle
Qiuran Wang, Michael R. Gau, Brian C. Manor, Patrick J. Carroll, Neil C. Tomson
European Journal of Inorganic Chemistry, 2023, 26, e202300335. DOI: 10.1002/ejic.202300335
+ Invited as part of a Special Collection on Inorganic Reaction Mechanisms.
+ Selected for inclusion in the Special Collection Evolving with Inorganic Chemistry for 25 Years.
41. Investigating Metal-Metal Bond Polarization in a Heteroleptic Tris-Ylide Diiron System
Ariana Z. Spentzos, Sam R. May, Alex M. Confer, Michael R. Gau, Patrick J. Carroll, David P. Goldberg, Neil C. Tomson
Inorganic Chemistry, 2023, 62, 11487-11499. DOI: 10.1021/acs.inorgchem.3c01068
40. C−C σ-Bond Oxidative Addition and Hydrofunctionalization by a Macrocycle-Supported Diiron Complex
Tianchang Liu, Ryan P. Murphy, Patrick J. Carroll, Michael R. Gau, Neil C. Tomson
Journal of the American Chemical Society, 2022, 144, 14037-14041. DOI: 10.1021/jacs.2c06266
39. Oriented Internal Electrostatic Fields: An Emerging Design Element in Coordination Chemistry and Catalysis
Alexander B. Weberg, Ryan P. Murphy, Neil C. Tomson
Chemical Science, 2022, 13, 5432-5446. DOI: 10.1039/D2SC01715F
+ Selected for inclusion in the 2022 Chemical Science HOT Article Collection.
38. Macrocycle-Induced Modulation of Internuclear Interactions in Homobimetallic Complexes
Laura M. Thierer, Sam H. Brooks, Alexander B. Weberg, Peng Cui, Shaoguang Zhang, Michael R. Gau, Brian C. Manor, Patrick J. Carroll, Neil C. Tomson
Inorganic Chemistry, 2022, 61, 6263–6280. DOI: 10.1021/acs.inorgchem.2c00522
37. Probing Ligand Effects on the Ultrafast Dynamics of Copper Complexes via Midinfrared Pump−Probe and 2DIR Spectroscopies
Wei Weng, Alexander B. Weberg, Rahul Gera, Neil C. Tomson, Jessica M. Anna
The Journal of Physical Chemistry B, 2021, 125, 12228–12241. DOI: 10.1021/acs.jpcb.1c06370
36. Mapping the Reactivity of Dicobalt Bridging Nitrides in Constrained Geometries
Ariana Z. Spentzos, Neil C. Tomson
Inorganic Chemistry, 2021, 60, 6889–6899. DOI: 10.1021/acs.inorgchem.0c03774
+ Invited as part of the Special Issue Heterogeneous Interfaces through the Lens of Inorganic Chemistry.
35. Tuning metal–metal interactions for cooperative small molecule activation
Qiuran Wang, Sam H. Brooks, Tianchang Liu, Neil C. Tomson
Chemical Communications, 2021, 57, 2839-2853. DOI: 10.1039/D0CC07721F
34. Pyridyldiimine macrocyclic ligands: Influences of template ion, linker length and imine substitution on ligand synthesis, structure and redox properties
Laura M. Thierer, Qiuran Wang, Sam H. Brooks, Peng Cui, Jia Qi, Michael R. Gau, Brian C. Manor, Patrick J. Carroll, Neil C. Tomson
Polyhedron, 2021, 198, 115044. DOI: 10.1016/j.poly.2021.115044
33. Using Internal Electrostatic Fields to Manipulate the Valence Manifolds of Copper Complexes
Alexander B. Weberg, Samuel P. McCollom, Laura M. Thierer, Michael R. Gau, Patrick J. Carroll, Neil C. Tomson
Chemical Science, 2021, 12, 4395-4404. DOI: 10.1039/D0SC06364A
32. Unusual cyanide and methyl binding modes at a dicobalt macrocycle following acetonitrile C–C bond activation
Ariana Z. Spentzos, Michael R. Gau, Patrick J. Carroll, Neil C. Tomson
Chemical Communications, 2020, 56, 9675-9678. DOI: 10.1039/D0CC03521A
31. Aryl Fluoride Activation Through Palladium-Magnesium Bimetallic Cooperation: A Mechanistic and Computational Study
Chen Wu, Samuel P. McCollom, Zhipeng Zheng, Jiadi Zhang, Sheng-Chun Sha, Minyan Li, Patrick J. Walsh, Neil C. Tomson
ACS Catalysis, 2020, 10, 7934-7944. DOI: 10.1021/acscatal.0c01301
30. N–H Bond Formation at a Diiron Bridging Nitride
Shaoguang Zhang, Peng Cui, Tianchang Liu, Qiuran Wang, Thomas. J. Longo, Laura M. Thierer, Brian C. Manor, Michael R. Gau, Patrick J. Carroll, Georgia C. Papaefthymiou, Neil C. Tomson
Angewandte Chemie International Edition, 2020, 59, 15215-15219. DOI: 10.1002/anie.202006391
29. Reversible Nickel-Metallacycle Formation with a Phosphinimine-based Pincer Ligand
Xiujing Xing, Shaoguang Zhang, Laura M. Thierer, Michael R. Gau, Patrick J. Carroll, Neil C. Tomson
Dalton Transactions, 2020, 49, 7796-7806. DOI: 10.1039/D0DT01118E
28. Mimicking the Constrained Geometry of a Nitrogen-Fixation Intermediate
Tianchang Liu, Michael R. Gau, Neil C. Tomson
Journal of the American Chemical Soceity, 2020, 142, 8142-8146. DOI: 10.1021/jacs.0c01861
27. Interdependent Metal−Metal Bonding and Ligand Redox-Activity in a Series of Dinuclear Macrocyclic Complexes of Iron, Cobalt, and Nickel
Qiuran Wang, Shaoguang Zhang, Peng Cui, Alexander B. Weberg, Laura M. Thierer, Brian C. Manor, Michael R. Gau, Patrick J. Carroll, Neil C. Tomson
Inorganic Chemistry, 2020, 59, 4200-4214. DOI: 10.1021/acs.inorgchem.9b02339
+ Selected as an ACS Editors’ Choice article and invited for the Front Cover of the associated issue of this journal.
26. Tuning Metal-Metal Interactions Through Reversible Ligand Folding in a Series of Dinuclear Iron Complexes
Shaoguang Zhang, Qiuran Wang, Laura M. Thierer, Alexander B. Weberg, Michael R. Gau, Patrick J. Carroll, Neil C. Tomson
Inorganic Chemistry, 2019, 58, 12234-12244. DOI: 10.1021/acs.inorgchem.9b01673
25. Ring Size Modulated Reactivity of Putative Dicobalt Bridging Nitrides: C-H Activation vs. Phosphinimide Formation
Peng Cui, Qiuran Wang, Samuel P. McCollom, Brian C. Manor, Patrick J. Carroll, Neil C. Tomson
Angewandte Chemie International Edition, 2017, 56, 15979-15983. DOI: 10.1002/anie.201708966
24. Palladium-Catalyzed Enantioselective Arylation of Aryl Sulfenate Anions: A Combined Experimental and Computational Study
Tiezheng Jia, Mengnan Zhang, Samuel P. McCollom, Ana Bellomo, Sonia Montel, Jianyou Mao, Spencer D. Dreher, Christopher J. Welch, Erik L. Regalado, R. Thomas Williamson, Brian C. Manor, Neil C. Tomson, Patrick J. Walsh
Journal of the American Chemical Society, 2017, 139, 8337-8345. DOI: 10.1021/jacs.7b03623
23. The Actinium Aqua Ion: A Century in the Making
Laura M. Thierer, Neil C. Tomson
ACS Central Science, 2017, 3, 153-155. DOI: 10.1021/acscentsci.7b00074
22. Voltage Clustering in Redox-Active Ligand Complexes: Mitigating Electronic Communication Through Choice of Metal Ion
Ryan A. Zarkesh, Andrew S. Ichimura, Todd C. Monson, Neil C. Tomson, Mitchell R. Anstey
Dalton Transactions, 2016, 45, 9962-9969. DOI: 10.1039/c6dt00422a
21. Positional Selectivity in C–H Functionalizations of 2-Benzyl Furans with Bimetallic Catalysts
Jiadi Zhang, Sheng-Chun Sha, Ana Bellomo, Nisalak Trongsiriwat, Feng Gao, Neil C. Tomson, Patrick J. Walsh
Journal of the American Chemical Society, 2016, 138, 4260-4266. DOI: 10.1021/jacs.6b01578
Prior to Penn
20. Oxidation of uranium(IV) mixed imido–amido complexes with PhEEPh and to generate uranium(VI) bis(imido) dichalcogenolates, U(NR)2(EPh)2(L)2
Neil C. Tomson, Nickolas H. Anderson, Aaron M. Tondreau, Brian L. Scott, James M. Boncella
Dalton Transactions, 2019, 48, 10865-10873. DOI: 10.1039/C9DT00680J
19. Ligand-directed Reactivity in Dioxygen and Water Binding to cis-[Pd(NHC)2(η2-O2)]
Taryn D. Palluccio, Xiaochen Cai, Subhojit Majumdar, Leonardo F. Serafim, Neil C. Tomson, Karl Wieghardt, Catherine S. J. Cazin, Steven P. Nolan, Elena V. Rybak-Akimova, Miguel Ángel Fernández-González, Manuel Temprado, Burjor Captain, and Carl D. Hoff
Journal of the American Chemical Society, 2018, 140, 264-276. DOI: 10.1021/jacs.7b09905
18. Crystal structure of 4,5-dinitro-1H-imidazole
G. Kenneth Windler, Brian L. Scott, Neil C. Tomson, Philip W. Leonard
Acta Crystallographica Section E: Crystallographic Communications, 2015, E71, o634. DOI: 10.1107/S2056989015013432
17. Crystal structure of 2-azido-1H-imidazole-4,5-dicarbonitrile
G. Kenneth Windler, Brian L. Scott, Neil C. Tomson, Philip W. Leonard
Acta Crystallographica Section E: Crystallographic Communications, 2015, E71, o633. DOI: 10.1107/S2056989015013444
16. A Linear trans-Bis(imido) Neptunium(V) Actinyl Analog: NpV(NDipp)2(tBu2bipy)2Cl (Dipp = 2,6-iPr2C6H3)
Jessie L. Brown, Enrique R. Batista, James M. Boncella, Andrew J. Gaunt, Sean D. Reilly, Brian L. Scott, and Neil C. Tomson
Journal of the American Chemical Society, 2015, 137, 9583-9586. DOI: 10.1021/jacs.5b06667
15. Re-evaluating the Cu K pre-edge XAS Transition in Complexes with Covalent Metal-Ligand Interactions
Neil C. Tomson, Kamille D. Williams, Xuliang Dai, Stephen Sproules, Serena DeBeer, Timothy H. Warren, Karl Wieghardt
Chemical Science, 2015, 6, 2474-2487. DOI: 10.1039/C4SC03294B
14. Preparation and Reactivity of the Versatile Uranium(IV) Imido Complexes U(NAr)Cl2(R2bpy)2 (R = Me, tBu) and U(NAr)Cl2(tppo)3
Robert E. Jilek, Neil C. Tomson, Ryan L. Shook, Brian L. Scott, James M. Boncella
Inorganic Chemistry, 2014, 53, 9818-9826. DOI: 10.1021/ic5014208
13. [2+2] Cycloaddition Reactions at Terminal Imido Uranium(IV) Complexes to Yield Isolable Cycloadducts
Robert E. Jilek, Neil C. Tomson, Brian L. Scott, James M. Boncella
Inorganica Chimica Acta, 2014, 422, 78-85. DOI: 10.1016/j.ica.2014.07.032
12. Application of Redox Non-Innocent Ligands to Non-aqueous Flow Battery Electrolytes
Patrick J. Cappillino, Harry D. Pratt III, Nicholas S. Hudak, Neil C. Tomson, Travis M. Anderson, Mitchell R. Anstey
Advanced Energy Materials, 2014, 4, 1300566. DOI: 10.1002/aenm.201300566
11. Diniobium Inverted Sandwich Complexes with μ-η6:η6-Arene Ligands: Synthesis, Kinetics of Formation, and Electronic Structure
Thomas L. Gianetti, Grégory Nocton, Stefan G. Minasian, Neil C. Tomson, A. L. David Kilcoyne, Stosh A. Kozimor, David K. Shuh, Tolek Tyliszczak, Robert G. Bergman, and John Arnold
Journal of the American Chemical Society, 2013, 135, 3224-3236. DOI: 10.1021/ja311966h
10. A step beyond the Feltham-Enemark notation: Spectroscopic and correlated ab initio computational support for an antiferromagnetically-coupled M(II)-(NO)- description of Tp*M(NO) (M = Co, Ni)
Neil C. Tomson, Mark R. Crimmin, Taras Petrenko, Lauren E. Rosebrugh, Stephen Sproules, W. Christopher Boyd, Robert G. Bergman, Serena DeBeer, F. Dean Toste, and Karl Wieghardt
Journal of the American Chemical Society, 2011, 133, 18785-18801. DOI: 10.1021/ja206042k
9. Stereoselective Catalytic Internal-Alkyne Semi-Hydrogenation under H2:CO Mixtures by a Niobium(III) Imido Complex
Thomas L. Gianetti, Neil C. Tomson, John Arnold, and Robert G. Bergman
Journal of the American Chemical Society, 2011, 133, 14904-14907. DOI: 10.1021/ja206016s
8. Redox Noninnocence of Nitrosoarene Ligands in Transition Metal Complexes
Neil C. Tomson, Liezel A. Labios, Thomas Weyhermüller, Joshua S. Figueroa, and Karl Wieghardt
Inorganic Chemistry, 2011, 50, 5763-5776. DOI: 10.1021/ic2005979
7. [(TMEDA)Co(NO)2][BPh4]: A Versatile Synthetic Entry Point to Four and Five Coordinate {Co(NO)2}10 Complexes
Mark R. Crimmin, Lauren E. Rosebrugh, Neil C. Tomson, Thomas Weyhermüller, Robert G. Bergman, F. Dean Toste, Karl Wieghardt
Journal of Organometallic Chemistry, 2011, 696, 3974-3981. DOI: 10.1016/j.jorganchem.2011.04.038
6. Synthesis, Characterization, and Reactivity of Cationic Niobium and Tantalum Methyl Complexes Supported by the Imido and β-Diketiminato Ligands
Neil C. Tomson, John Arnold, Robert G. Bergman
Dalton Transactions, 2011, 40, 7718-7729. DOI: 10.1039/C1DT10202H
5. Synthesis, Characterization, and Reactivity of Isolable (β-Diketiminato) Nb(III) Imido Complexes
Neil C. Tomson, John Arnold, Robert G. Bergman
Organometallics, 2010, 29, 5010-5025. DOI: 10.1021/om1002528
4. Halo, Alkyl, Aryl, and Bis(imido) Complexes of Niobium Supported by the β-Diketiminato Ligand
Neil C. Tomson, John Arnold, Robert G. Bergman
Organometallics, 2010, 29, 2926-2942. DOI: 10.1021/om1001827
3. An Unusually Diverse Array of Products Formed Upon Carbonylation of a Dialkyl Niobium Complex
Neil C. Tomson, Andrew Yan, John Arnold, Robert G. Bergman
Journal of the American Chemical Society, 2008, 130, 11262-11263. DOI: 10.1021/ja803729k
2. 1JWSn as a Solution State Predictor for Tungsten-Tin Solid State Bond Length in Sterically Crowded Tungstenocene Stannyl Complexes
T. Andrew Mobley, Rochelle Gandour, Eric P. Gillis, Kwame Nti-Addae, Rahul Palchaudhuri, Presha Rajbhandari, Neil Tomson, Angel Vargas, Qi Zheng
Organometallics, 2005, 24, 3897-3906. DOI: 10.1021/om049006d
1. Dithiocarbamate Precursors for Rare-Earth Sulfides
Michelle D. Regulacio, Neil Tomson, Sarah L. Stoll
Chemistry of Materials, 2005, 17, 3114-3121. DOI: 10.1021/cm0478071