Pre-prints and Submitted Manuscripts


2022:

 

41. Weberg, A. B.; McCollom, S. P.; Tomson, N. C. “Electrosteric Stabilization of End-on Cupric Superoxide Complexes” Pre-print available on Chemrxiv, doi: 10.26434/chemrxiv-2022-63pfg 10.26434/chemrxiv-2022-63pfg


 

40. Weberg, A. B.; McCollom, S. P.; Murphy, R. P.; Tomson, N. C. “Electrostatic Contributions to the Stability of an End-on Cupric Superoxide” Submitted, 2022. Pre-print available on Chemrxiv, doi: 10.26434/chemrxiv-2022-lcb1w doi: 10.26434/chemrxiv-2022-lcb1w


Publications


At Penn:


2022:


 

39. Weberg, A. B.; Murphy, R. P.; Tomson, N. C. “Oriented Internal Electrostatic Fields: An Emerging Design Element in Coordination Chemistry and Catalysis” Chem. Sci., 2022, Accepted


 

38. Thierer, L. M.; Brooks, S. H.; Weberg, A. B.; Cui, P.; Zhang, S.; Gau, M. R.; Manor, B. C.; Carroll, P. J.; Tomson, N. C. “Macrocycle-Induced Modulation of Internuclear Interactions in Homobimetallic Complexes” Inorg. Chem. 2022, 61, 16, 6263–6280 DOI: 10.1021/acs.inorgchem.2c00522


2021:


 

37. Weng, W.; Weberg, A. B.; Gera, R.; Tomson, N. C.; Anna, J. M., "Probing Ligand Effects on the Ultrafast Dynamics of Copper Complexes via Midinfrared Pump−Probe and 2DIR Spectroscopies" J. Phys. Chem. B, 2021, 125, 44, 12228–12241 DOI: 10.1021/acs.jpcb.1c06370


 

36. Spentzos, A. Z.; Tomson, N. C. "Mapping the Reactivity of Dicobalt Bridging Nitrides in Constrained Geometries" Inorg. Chem., 2021, 60, 10, 6889–6899 DOI: 10.1021/acs.inorgchem.0c03774


 

35. Wang, Q.; Brooks, S. H.†; Liu, T.†; Tomson, N. C. "Tuning metal–metal interactions for cooperative small molecule activation" Chem. Commun., 2021,57, 2839-2853 DOI: 10.1039/D0CC07721F


 

34. Thierer, L. M.; Wang, Q.; Brooks, S. H.; Cui, P.; Qi, J.; Gau, M. R.; Manor, B. C.; Carroll, P. J.; Tomson, N. C. "Pyridyldiimine macrocyclic ligands: Influences of template ion, linker length and imine substitution on ligand synthesis, structure and redox properties" Polyhedron, 2021, Accepted DOI: 10.1016/j.poly.2021.115044


 

33. Weberg, A. B.; McCollom, S. P.; Thierer, L. M.; Gau, M. R.; Carroll, P. J.; Tomson, N. C. “Using Internal Electrostatic Fields to Manipulate the Valence Manifolds of Copper Complexes” Chem. Sci., 2021,12, 4395-4404 DOI: 10.1039/D0SC06364A


2020:


 

32. Spentzos, A. Z.; Gau, M. R.; Carroll, P. J.; Tomson, N. C. “Unusual cyanide and methyl binding modes at a dicobalt macrocycle following acetonitrile C–C bond activation” Chem Commun, 2020, 56, 9675 - 9678 DOI: 10.1039/D0CC03521A


 

31. Wu, C.; McCollom, S. P.; Zheng, Z.; Zhang, J.; Sha, S.; Li, M.; Walsh, P. J. and Tomson, N. C. “Aryl Fluoride Activation Through Palladium-Magnesium Bimetallic Cooperation: A Mechanistic and Computational Study” ACS Catal. 2020, 10, 14, 7934 - 7944 DOI: 10.1021/acscatal.0c01301


 

30. Zhang, S.; Cui, P.; Liu, T.; Wang, Q.; Longo, T. J.; Thierer, L. M.; Manor, B. C.; Gau, M. R.; Carroll, P. J.; Papaefthymiou, G. C.; Tomson, N. C. “N–H Bond Formation at a Diiron Bridging Nitride” Angew. Chem. Int. Ed. 2020, 59, 15215 DOI: 10.1002/anie.202006391


 

29. Xing, X.; Zhang, S.; Thierer, L. M.; Gau, M. R.; Carroll, P. J.; Tomson, N. C. “Reversible Nickel-Metallacycle Formation with a Phosphinimine-based Pincer Ligand” Dalton Trans. 2020, 49, 7796 - 7806 DOI: 10.1039/D0DT01118E


 

28. Liu, T.; Gau, M. R.; Tomson, N. C. “Mimicking the Constrained Geometry of a Nitrogen-Fixation Intermediate” J. Am. Chem. Soc. 2020, 142, 18, 8142 - 8146 DOI: 10.1021/jacs.0c01861


 

27. Wang, Q.; Zhang, S.; Cui, P.; Weberg, A. B.; Thierer, L. M.; Manor, B. C.; Gau, M. R.; Carroll, P. J.; Tomson, N. C. “Interdependent Metal−Metal Bonding and Ligand Redox-Activity in a Series of Dinuclear Macrocyclic Complexes of Iron, Cobalt, and Nickel” Inorg. Chem. 2020, 59, 7, 4200 - 4214 DOI: 10.1021/acs.inorgchem.9b02339


2019:

 

26. Zhang, S.; Wang, Q.; Thierer, L. M.; Weberg, A. B.; Gau, M. R.; Carroll, P. J.; Tomson, N. C. "Tuning Metal-Metal Interactions Through Reversible Ligand Folding in a Series of Dinuclear Iron Complexes" Inorg. Chem. 2019, 58, 18, 12234 - 12244 DOI: 10.1021/acs.inorgchem.9b01673


2017:

 

25. Cui, P.; Wang, Q.; McCollom, S. P.; Manor, B. C.; Carroll, P. J.; Tomson, N. C. "Ring Size Modulated Reactivity of Putative Dicobalt Bridging Nitrides: C-H Activation vs. Phosphinimide Formation" Angew. Chem. Int. Ed. 2017, 56, 15979-15983 DOI: 10.1002/anie.201708966


 

24. Jia, T.; Zhang, M.; McCollom, S. P.; Bellomo, A.; Montel, S.; Mao, J.; Dreher, S. D.; Welch, C. J.; Regalado, E. L.; Williamson, R. T.; Manor, B. C.; Tomson, N. C.; Walsh, P. J. "Palladium-Catalyzed Enantioselective Arylation of Aryl Sulfenate Anions: A Combined Experimental and Computational Study" J. Am. Chem. Soc. 2017, 139 (24), 8337-8345 DOI: 10.1021/jacs.7b03623


 

23. Thierer, L. M.; Tomson, N. C. "The Actinium Aqua Ion: A Century in the Making" ACS Cent. Sci. 2017, 3 (3), 153-155 DOI: 10.1021/acscentsci.7b00074


2016:

 

22. Zarkesh, R. A.; Ichimura, A. S.; Monson, T.; Tomson, N. C.; Anstey, M. R. "Voltage Clustering in Redox-Active Ligand Complexes: Mitigating Electronic Communication Through Choice of Metal Ion” Dalton Trans. 2016, 45, 9962-9969 DOI: 10.1039/c6dt00422a


 

21. Zhang, J.; Sha, S.-C.; Bellomo, A.; Trongsiriwat, N.; Gao, F.; Tomson, N. C.; Walsh, P. J. "Positional Selectivity in C–H Functionalizations of 2-Benzyl Furans with Bimetallic Catalysts” J. Am. Chem. Soc. 2016, 138 (12), 4260-4266 DOI: 10.1021/jacs.6b01578


Prior to Penn:

20. Tomson, N. C.; Anderson, N. H.; Tondreau, A. M.; Scott, B. L.; Boncella, J. M. "Oxidation of uranium(IV) mixed imido–amido complexes with PhEEPh and to generate uranium(VI) bis(imido) dichalcogenolates, U(NR)2(EPh)2(L)2" Dalton Trans. 2019 DOI: 10.1039/C9DT00680J

19. Pallaccio, T. D.; Cai, X.; Majumdar, S.; Serafim, J. F.; Tomson, N. C., Wieghardt, K.; Cazin, C. S. J.; Nolan, S. P.; Rybak-Akimova, E. V.; Fernandez-Gonzalez, M. A.; Temprado, M.; Captain, B.; Hoff, C. D. "Ligand-directed Reactivity in Dioxygen and Water Binding to cis-[Pd(NHC)22-O2)]" J. Am. Chem. Soc. 2018, 140 (1), 264-276 DOI: 10.1021/jacs.7b09905

18. Windler, G. K.; Scott, B. L.; Tomson, N. C.; Leonard, P. L.* “Crystal structure of 4,5-dinitro-1H-imidazole” Acta Cryst. 2015, E71, o634. DOI: 10.1107/S2056989015013432

17. Windler, G. K.; Scott, B. L.; Tomson, N. C.; Leonard, P. L.* “Crystal structure of 2-azido-1H-imidazole-4,5-dicarbonitrile” Acta Cryst. 2015, E71, o633. DOI: 10.1107/S2056989015013444

16. Brown, J. L.; Batista, E. R.; Boncella, J. M.; Gaunt, A. J.; Reilly, S. D.; Scott, B. L.; Tomson, N. C. “A Linear trans-Bis(imido) Neptunium(V) Actinyl Analog: NpV(NDipp)2(tBu2bipy)2Cl (Dipp = 2,6-iPr2C6H3)” J. Am. Chem. Soc. 2015, 137, 9583-9586. DOI: 10.1021/jacs.5b06667

15. Tomson, N. C.; Williams, K. D.; Dai, X.; Sproules, S. S.; DeBeer, S.; Warren, T. H.; Wieghardt, K. “Re-evaluating the Cu K pre-edge XAS Transition in Complexes with Covalent Metal-Ligand Interactions” Chem. Sci. 2015, 6, 2474-2487. DOI: 10.1039/C4SC03294B

14. Jilek, R. E.; Tomson, N. C.; Shook, R. L.; Scott, B. L.; Boncella, J. M. “Preparation and Reactivity of the Versatile Uranium (IV) Imido Complexes U(NAr)Cl2(R2bpy)2 (R = Me, tBu) and U(NAr)Cl2(tppo)3” Inorg. Chem. 2014, 53, 9818-9826. DOI: 10.1021/ic5014208

13. Jilek, R. E.; Tomson, N. C.; Scott, B. L.; Boncella, J. M. “[2+2] Cycloaddition Reactions at Terminal Imido Uranium(IV) Complexes to Yield Isolable Cycloadducts” Inorg. Chim. Acta 2014, 422, 78-85. DOI: 10.1016/j.ica.2014.07.032

12. Cappillino, P. J.; Pratt, H. D., III; Hudak, N. S.; Tomson, N. C.; Anderson, T. M.; Anstey, M. R. “Application of Redox Non-Innocent Ligands to Non-aqueous Flow Battery Electrolytes” Adv. Energy Mater. 2014, 4, 1300566. DOI: 10.1002/aenm.201300566

11. Gianetti, T. L.; Nocton, G.; Minasian, S. G.; Tomson, N. C.; Kilcoyne, A. L. D.; Kozimor, S. A.; Shuh, D. K.; Tyliszczak; Bergman, R. G.; Arnold, J. “Diniobium Inverted Sandwich Complexes with μ-η66-Arene Ligands: Synthesis, Kinetics of Formation, and Electronic Structure” J. Am. Chem. Soc. 2013, 135, 3224-3236. DOI: 10.1021/ja311966h

10. Tomson, N. C.; Crimmin, M. R.; Petrenko, T.; Rosebrugh, L. E.; Sproules, S.; Boyd, W. C.; Bergman, R. G.; DeBeer, S.; Toste, F. D.; Wieghardt, K. “A step beyond the Feltham-Enemark notation: Spectroscopic and correlated ab initio computational support for an antiferromagnetically-coupled M(II)-(NO)- description of Tp*M(NO) (M = Co, Ni)” J. Am. Chem. Soc. 2011, 133, 18785-18801. DOI: 10.1021/ja206042k

9. Gianetti, T. L.; Tomson, N. C.; Arnold, J.; Bergman, R. G. “Stereoselective Catalytic Internal-Alkyne Semi-Hydrogenation under H2:CO Mixtures by a Niobium(III) Imido Complex” J. Am. Chem. Soc. 2011, 133, 14904-14907. DOI: 10.1021/ja206016s

8. Tomson, N. C.; Labios, L. A.; Weyhermüller, T.; Figueroa, J. S.; Wieghardt, K. “Redox Noninnocence of Nitrosoarene Ligands in Transition Metal Complexes” Inorg. Chem. 2011, 50, 5763-5776. DOI: 10.1021/ic2005979

7. Crimmin, M. R.; Rosebrugh, L. E.; Tomson, N. C.; Weyhermüller, T.; Bergman, R. G.; Toste, F. D.; Wieghardt, K. “[(TMEDA)Co(NO)2][BPh4]: A Versatile Synthetic Entry Point to Four and Five Coordinate {Co(NO)2}10 Complexes” J. Organomet. Chem. 2011, 696, 3974-3981. DOI: 10.1016/j.jorganchem.2011.04.038

6. Tomson, N. C.; Arnold, J.; Bergman, R. G. “Synthesis, Characterization, and Reactivity of Cationic Niobium and Tantalum Methyl Complexes Supported by the Imido and β-Diketiminato Ligands” Dalton Trans. 2011, 40, 7718-7729. DOI: 10.1039/C1DT10202H

5. Tomson, N. C.; Arnold, J.; Bergman, R. G. “Synthesis, Characterization, and Reactivity of Isolable (β-Diketiminato) Nb(III) Imido Complexes” Organometallics 2010, 29, 5010-5025. DOI: 10.1021/om1002528

4. Tomson, N. C.; Arnold, J.; Bergman, R. G. “Halo, Alkyl, Aryl, and Bis(imido) Complexes of Niobium Supported by the β-Diketiminato Ligand” Organometallics 2010, 29, 2926-2942. DOI: 10.1021/om1001827

3. Tomson, N. C.; Yan, A.; Arnold, J.; Bergman, R. G. “An Unusually Diverse Array of Products Formed Upon Carbonylation of a Dialkyl Niobium Complex” J. Am. Chem. Soc. 2008, 130, 11262-11263. DOI: 10.1021/ja803729k

2. Mobley, T. A.; Gandour, R.; Gillis, E. P.; Nti-Addae, K.; Palchaudhuri, R.; Rajbhandari, P.; Tomson, N.; Vargas, A.; Zheng, Q. “1JWSn as a Solution State Predictor for Tungsten-Tin Solid State Bond Length in Sterically Crowded Tungstenocene Stannyl Complexes” Organometallics 2005, 24, 3897-3906. DOI: 10.1021/om049006d

1. Regulacio, M. D.; Tomson, N.; Stoll, S. L. “Dithiocarbamate Precursors for Rare-Earth Sulfides” Chem. Mater. 2005, 17, 3114-3121. DOI: 10.1021/cm0478071


Neil C. Tomson

Department of Chemistry, IAST 3002
University of Pennsylvania
231 South 34th Street, Philadelphia, PA 19104-6323

: (215) 898-6208
: Neil C. Tomson

Copyright © Neil C. Tomson 2015